Modeling of the particle scattering structure factor for branched bio-polymers in solution: A X-ray scattering study

Authors

  • P. Calandra CNR-IPCF
  • M. A. Kiselev
  • D. Lombardo

DOI:

https://doi.org/10.1478/C1V89S1P020

Abstract

We present a study which illustrates the modeling of the Particle Scattering Structure Factor from Small Angle X-ray Scattering (SAXS) data. The studied sample was a poly(amidoamine) Pamam dendrimers in water solution. The intra-particle form factor P(q) has been analyzed employing an inverse Fourier transformation which allows to obtain the particle pair distance distribution function and to gain information about dendrimer shape. The experimental inter-dendrimer structure factor S(q) has been analysed in the framework of liquid integral equation theory for charged systems in solution. From that, we derive an effective interparticle interaction composed of a screened Coulombic plus hard-sphere repulsion potential, which allow the estimation of the dendrimer effective surface charge Zeff. The present analysis, applied to a Pamam dendrimers in water solution, strongly supports the finding that structures and interaction of dendrimer is strongly influenced by charge effects. As a result, this quantity can be considered as a crucial parameters for the modulation of the degree of structural organization in solution, suitable for a number of potential applications.
Mount Aetna from Taormina by Thomas Cole (1843)

Downloads

Published

2011-09-15

Issue

Vol 89, SUPPLEMENT NO 1 (2011): ELS XIII Conference

Section

Past Conference Papers

License

Creative Commons License
This work is licensed under a Creative Commons Attribution 4.0 International License.

Authors who publish with this journal agree to the following terms:
  • Authors retain copyright and grant the journal right of first publication with the work simultaneously licensed under a Creative Commons Attribution License that allows others to share the work with an acknowledgement of the work's authorship and initial publication in this journal.
  • Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgement of its initial publication in this journal.
  • Authors are permitted and encouraged to post their work online (e.g., in institutional repositories or on their website) prior to and during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work (See The Effect of Open Access).